In-Situ RDO Sensor

Announcement of new Optical Dissolved Oxygen Sensor

Features

  • Rugged, with Titanium or Delrin design
  • Flood proof
  • No membranes, no electrolyte
  • Low drift
  • Fast and stable response

Ordering Information
Sales Index  
Water Quality Instruments  

Related Products
TROLL 9500

Related to this product


 

The new RDO sensor utilizes recent advances in lifetime-based optical fluorescence sensor technology to provide an extremely stable, precise and low maintenance dissolved oxygen senor.

This technology stands to revolutionize the current methods of water quality monitoring by eliminating the need for membranes, stirring, and cleaning while allowing deployment for many months without need for recalibration.

 

Features:
  • High precision and accuracy. Measure absolute oxygen concentrations without field calibrations
  • Integrates directly into the TROLL 9000 with Smart Sensor technology - "Plug & Play"
  • No membranes / No electrolyte
  • 5 years / 5 Million readings before lumiphore is exhausted
  • Up to 1 year between calibrations
  • Minimal maintenance / no hazardous cleaning solutions
  • No flow requirements
  • Fast and stable response
  • Low drift
  • Excellent performance in anoxic conditions (0 ppm)
  • Not "poisoned" by Sulfides
  • Not subject to "thermal shocking"
  • No cross sensitivity to: H2S, pH, CO2, NH3, SO4-, Cl-, Cl2, ClO2, MeOH, EtOH, various ionic species
Two options are available:
Titanium or Delrin

30 Day no risk guarantee!! If you don't like it after 30 days just return, for full credit.
When making critical decisions based on D.O., which data would
you rather see?
The data on the left is from a traditional Clark-electrode, while the one on the right is from an RDO sensor. Surprisingly, this data is from the same sample. So why the difference? The truth is that so many factors can influence the readings of a Clark-electrode and without good experience, it is had to get good data. Optical D.O. can obtain the correct results without all the hassle. This is why this new technology is so exciting!
RDO Sensor Installation
Rugged Construction with Flexible Installation
The powerful Rugged Dissolved Oxygen sensor ("RDO") with optical technology means peace of mind with dissolved oxygen monitoring. It is available as an optional sensor that plugs right into new and existing TROLL 9000s and TROLL 9500s. The design makes it easy to add or remove and can be used any time you require high quality D.O. readings without the hassle.
Technology addresses the age-old problem with D.O.

Dissolved Oxygen (DO) is one of the single most important parameters monitored when examining aquatic biology and related processes. Until recently the ability to accurately monitor dissolved oxygen levels over long periods of time was limited. Existing electrochemical sensors (Clark, Galvanic) require sample stirring and are functionally limited by the durability of their membrane and electrode, while galvanic diffusion types offer characteristically slow response.
The new RDO sensor provides superior performance to traditional DO sensing technology currently on the market.

 

The micro-optical technology incorporated in the RDO sensor centers around the extensively field-proven methodology of Lifetime-based Luminescent Dissolved Oxygen detection.

This solid-state method uses LEDs to excite a fluorescent material, while an optical receptor gauges the duration, or lifetime, of the event. The duration of fluorescence is inversely proportional to the ambient amount of dissolved oxygen in the water.

Environmental Industry interest in the RDO sensor is centered around the fact that in many instances it can remain deployed through entire testing seasons - spanning months without

calibration; at the same time retaining its accuracy in even the harshest of fouling environments, without the need for stirring.

All dissolved oxygen sensors are affected by active bio-fouling. Optical D.O. technology is also affected by fouling in the sense that the actual D.O. levels may be increased or decreased around the sensing element. However, the difference is that an optical D.O. sensor can simply be cleaned and redeployed with NO need for recalibration.

When viewed from the bottom line, benefits of this sensor are not only the time/money saved with freedom from calibration, but also notably reliable and accurate test data.


Compare the old and the new:

Why Optical D.O.?
The new RDO sensor is to the Clark cell what the computer was to the typewriter.
Now you can:
  • Reliably measure oxygen concentration with accuracy and precision
  • Eliminate the need for flow/stirring
  • Eliminate the need for changing membranes and electrolyte
  • Eliminates unwanted temperature effects
  • Eliminate the need for complex sensor storage and conditioning

ANSWER: Higher quality data at a lower cost of ownership


Old Clark - style DO sensor                 New Rugged DO sensor
Optical D.O. Technology - how does it work?


 

  • The sensing element (luminophore) is activated, or excited when illuminated with a blue light
  • When activated, the sensor emits red light in an intensity that is inversely proportional to the amount of oxygen present in the water
  • There is also a time delay between the peak emission of blue light and peak response of fluoresced red light. The amount of delay is inversely proportional to the amount of oxygen present.
  • This time delay can be expressed as a phase shift between the wave patterns of incident blue light and the fluoresced red light
3 ways to measure using optics:
1. Magnitude -- Not very good. Interference from ambient light.

2. Time Domain -- Good, but subject to errors due to problems with peak detection. Signal to noise ratio
    limits range.

3. Phase Domain -- Best. Lock-in amplifier determines phase angle based on entire signal and reference
    wave forms. Magnitude is not important, greater operating range. This is the method used by RDO!
RDO does not require stirring

Graph shows test of Clark electrode vs. an RDO sensor with and without stirring. Notice how the Clark-electrode is adversely affected when stirring is turned off while the RDO is continue to display the correct reading.
How does photo bleaching affect optical D.O. sensors?
After two days of direct sunlight exposure, the RDO sensor still measures accurately. Though this cannot be said for some of the other optical D.O. technologies on the market.
7 RDO sensor match precisely with Winkler Titrations and other lab methods
Testing Results
Extensively Field Proven
Successfully tested and deployed over 300 sensors in the following environments:

Deployments/Usages:

Harsh environments:
  • Fresh water applications
  • Brackish water
  • Dirty water
  • Ground-water
  • Waste streams

Oceanic application:

  • Depths of up to 6000 meters
  • High salinity
  • Low temperature
  • Long-term deployment (greater than 6 months)
3rd Party Testing - RDO shows superior accuracy & stability:
ACT Evaluation - Summary of Results (the following table was generated by In-Situ based on ACT data)

Parameter

Winkler Titration Method

Optical Fluorescence Method

Polarographic Electrochemical Method

Galvanic Electrochemical Method

 

Average Initial

(reference method)

0.2mg/L

0.5mg/L

0.2mg/L

How accurate was it at the beginning?

Frequency of Initial Errors
<0.2mg/L

(reference method)

50%

40%

10%

Frequency of Initial Errors
<2.0mg/L

(reference method)

0%

10%

60%

Individual Precision

0.22%

0.11%

0.11%

0.15%

 

Typical drift during first week, mg/L

(reference method)

0.4mg/L

0.7mg/L

1.0mg/L

How bad was the drift?

Variability of drift

(reference method)

0.6mg/L

3.9mg/L

0.7mg/L

The RDO was selected to participate in a study funded by the Alliance for Coastal Technologies to research advances in D.O. measurement technology.The Alliance for Coastal Technologies, a NOAA funded partnership of research institutions, state and regional resource managers, and private sector companies interested in developing and applying sensor technologies for monitoring and studying coastal environments. One of the aims of the ACT organization is to work as a test-bed for evaluating new and developing coastal sensor and sensor platform technologies. The first tests performed by ACT focused on evaluating different oxygen sensing technologies.

Tests were done at seven different field sites (one month at each) and in the laboratory.
Full report can be downloaded at:
http://www.act-us.info/evaluation_reports.php
 
Specifications:

Item

Specification

Accuracy & precision

±0.1mg/L or ±0.1% of reading, whichever is greater

Operating range

0-20mg/L or 0-450% saturation

Temperature range (operating/ storage)

0 - 40°C / -40°C - 80°C
salinity range Up to 40ppt
pH range 0 - 12 pH
Typical response limit >25mg/L
Response time T90 = 16 seconds, oxygen increasing
Technology Flourophor impregnated membrane optical sensor, dynamic luminescence quenching technique
Calibration 1 point or 2 point
Typical calibration duration 12 months (clean water)
Known inferences SO2, C12
Chemical exposure Safe with methanol and ethanol. Avoid other organic solvents
Materials Titanium or 316L Stainless steel/ Delrin
Senor foil technology Platinum Porphyrine Luminophore embedded in polyester
Sensor foil coating Teflon
Sensor foil like/ RDO warranty 5 years at 10 second intervals / 1 year
Typical foil service life 13 million measurements
Power requirements 1 long life lithium, 4 alkaline D-call batteries, or ext power
Dimensions, RDO sensor 36mm OD, 89mm long
RDO sensor adapter assembly 88.4mm OD, 20.3cm long
 


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